Tailoring Mesoporous Silicon Surface to Form a Versatile Template for Nanoparticle Deposition

نویسندگان

چکیده

Porous silicon (PS) can be used as a loading template in sensing or matrix to develop nanoparticle arrays. We present comprehensive study of PS morphology and optical properties before after the pore opening process, including determination thickness, size, density layers, its surface wettability, reflectivity. The samples were fabricated by electrochemical anodization monocrystalline wafer 5–20 wt.% hydrofluoric acid (HF) solution at current range 20–200 mA/cm2. Anodization was followed i.e., removal parasitic superficial layer with “bottleneck” structure reactive ion etching (RIE). results illustrate that “bottleneck”-free allows achieve high using low HF concentration reduced density. established this demonstrates higher hydrophobicity comparison RIE. applicability developed tested via filling pores silver nanoparticles, indicating potential use for fabrication

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Tailoring the degradation kinetics of mesoporous silicon structures through PEGylation.

Injectable and implantable porosified silicon (pSi) carriers and devices for prolonged and controlled delivery of biotherapeutics offer great promise for treatment of various chronic ailments and acute conditions. Polyethylene glycols (PEGs) are important surface modifiers currently used in clinic mostly to avoid uptake of particulates by reticulo-endothelial system (RES). In this work we show ...

متن کامل

A flexible, bolaamphiphilic template for mesoporous silicas.

A novel symmetrical bolaamphiphile, containing two N-methylimidazolium head-groups bridged by a 32-methylene linker, was synthesized and characterized. A variety of mesoporous silicas was prepared using the bolaamphiphile as a "soft template". The effects of absolute surfactant concentration and synthesis conditions upon the morphologies of these silicas were investigated. For a given surfactan...

متن کامل

A Soft and Efficient Approach for Removal of Template from Mesoporous Silica using Benzene Sulfonamide

In this contribution, an effective and soft method for removal of template from nanochannels of mesoporous silica (MCM-41) is proposed. This method is based on chemically-modified solvent extraction which enhanced by means of an auxiliary organic compound, i.e. benzene sulfonamide. Template removal was performed in soft condition, i.e. in the presence of diluted sulfuric acid and at ambient tem...

متن کامل

Palladium nanoparticle deposition via precipitation: a new method to functionalize macroporous silicon

We present an original two-step method for the deposition via precipitation of Pd nanoparticles into macroporous silicon. The method consists in immersing a macroporous silicon sample in a PdCl2/DMSO solution and then in annealing the sample at a high temperature. The impact of composition and concentration of the solution and annealing time on the nanoparticle characteristics is investigated. ...

متن کامل

Facile synthesis of highly ordered mesoporous silver using cubic mesoporous silica template with controlled surface hydrophobicityw

Recently, there has been great interest in the synthesis and application of various kinds of nanostructured noble metals such as platinum, gold and silver. Nanostructured silvers have been widely investigated as antimicrobial materials, bio-sensors, catalysts, and advanced materials exhibiting surface plasmon resonance and surface enhanced Raman scattering. All this research is mainly based on ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Coatings

سال: 2021

ISSN: ['2079-6412']

DOI: https://doi.org/10.3390/coatings11060699